THE EFFECT OF ISOELECTRIC AMINO ACIDS ON THE pH+ OF A PHOSPHATE BUFFER SOLUTION
نویسندگان
چکیده
The relative merits of the classical conception and of the Zwitter Ion conception of the dissociation of amphoteric electrolytes are discussed, and the following data are presented which confirm the Zwitter Ion hypothesis of Bjerrum, and which are not in accord with the classical view. 1. Amino acids in the isoelectric form resemble strong electrolytes in that they contribute to the ionic strength of the solution. 2. The dielectric constants of aqueous solutions of amino acids, like those of solutions of strong electrolytes greater than 0.02 normal, are considerably greater than that of pure water. 3. The magnitude of the dissociation constants of substituted acetic acids and of glycine, are more easily accounted for with the Zwitter Ion than with the classical conception.
منابع مشابه
THE EFFECT OF ISOELECTRIC AMINO ACIDS ON THE pH + OF A PHOSPHATE BUFFER SOLUTION A CONTRIBUTION IN SUPPORT OF THE ((ZWlTTER ION" HYPOTHESIS BY HENRY BORSOOK AND DOUGLAS
In recent years the conception in biochemistry of the ionization of amphoterie electrolytes developed by Walker (1) which is still generally accepted, has been gradually losing ground. The tendency has been to replace it with the hypothesis of Bredig (2), Adams (3) and Bjerrum (4), commonly designated as the "Zwitter Ion" hypothesis. The difference between the two hypotheses is represented by t...
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عنوان ژورنال:
- The Journal of General Physiology
دوره 13 شماره
صفحات -
تاریخ انتشار 2003